Bis(triphenylphosphine)iminium chloride is the chemical compound with the formula [((C6H5)3P)2N]Cl, often abbreviated [(Ph3P)2N]Cl, where Ph is phenyl C6H5, or even abbreviated [PPN]Cl or [PNP]Cl or PPNCl or PNPCl, where PPN or PNP stands for (Ph3P)2N. This colorless salt is a source of the … See more [(Ph3P)2N]Cl is prepared in two steps from triphenylphosphine Ph3P: Ph3P + Cl2 → Ph3PCl2 This triphenylphosphine dichloride Ph3PCl2 is related to phosphorus pentachloride PCl5. Treatment of … See more In the laboratory, [(Ph3P)2N]Cl is the main precursor to [(Ph3P)2N] salts. Using salt metathesis reactions, nitrite, azide, and other small inorganic anions can be obtained with [(Ph3P)2N] cations. The resulting salts [(Ph3P)2N] NO−2, [(Ph3P)2N] N−3, … See more A phosphazenium cation related to [(Ph3P)2N] is [(((CH3)2N)3P)2N] . See more WebA binary catalyst system, 1-Cl with bis (triphenylphosphine)iminium chloride (PPNCl), showed a TOF of 1600 h −1, producing a smaller size of PCHC under otherwise the same reaction conditions (entry 7), which …
Synthesis of polyethers from epoxides via a binary organocatalyst ...
WebJan 12, 2024 · Chemsrc provides Bis (triphenylphosphine)iminium chloride (CAS#:21050-13-5) MSDS, density, melting point, boiling point, … WebA stable trigonal bipyramidal copper(III) complex, [PPN][Cu(TMSPS3)Cl] (1, wherein PPN represents bis(triphenylphosphine)iminium), was synthesized from CuCl2/PPNCl via intramolecular copper(II) disproportionation. birdwood golf course rates
Bis(triphenylphosphine)iminium borohydride
WebMar 29, 2024 · bis(triphenylphosphine)iminium cation prevents the formation of hydrogen bond interactions with the anionic part of the compounds. This behavior has also been shown in the case of the crystal ... WebWe have prepared a new salt of the solvatochromic [Ru(bpy)(CN) 4] 2-anion bis(triphenylphosphine)iminium 2,2‘-bipyridyltetracyanoruthenate, ((PPN) 2 … WebDec 1, 2010 · Bis(triphenylphosphine)iminium bromide acetonitrile monosolvate December 2010 · Acta Crystallographica Section E: Crystallographic Communications Carsten Knapp birdwood golf course charlottesville